OK there were no connectors - I had assumed that Exchange 2019 was built for hybrid, but I guess that was just making an ass of myself..
When I try and create a send to exchange on premise server, I am getting;
450 4.4.317 Cannot connect to remote server [Message=UntrustedRoot] [LastAttemptedServerName=mail.domain.suffix] [LastAttemptedIP=x.x.x.x:25] [LO2GBR01FT025.eop-gbr01.prod.protection.outlook.com]